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Steroid hormones are a prevalent aquatic micropollutant that poses risks to human health and the environment. Researchers at KIT have studied the degradation of these hormones in an electrochemical membrane reactor with carbon nanotube membranes. Their findings, published in Nature Communications, reveal that adsorption of steroid hormones on the carbon nanotubes does not hinder their subsequent degradation. With the increasing presence of micropollutants in wastewater, finding effective methods to remove them is crucial for providing clean water to people globally.

Endocrine-disrupting substances, such as steroid hormones, are challenging to detect and remove using traditional water treatment methods. Electrochemical oxidation (EO) has emerged as a promising technique for removing these substances by utilizing an anode and cathode connected to an external power source. Electrochemical membrane reactors (EMR) enhance the efficiency of electrochemical oxidation by utilizing a conductive membrane as a flow-through electrode, improving mass transfer and accessibility of active sites for reacting molecules. This approach has shown potential for degrading micropollutants like steroid hormones in water.

The collaboration between KIT, University of California – Los Angeles, and Hebrew University of Jerusalem has shed light on the mechanisms at play in EMRs. In their study published in “Water Treatment and Harvesting,” the researchers investigated the degradation of steroid hormone micropollutants in an EMR with carbon nanotube membranes. Carbon nanotubes possess unique physical and chemical properties, including high electrical conductivity and a large surface area for adsorbing organic compounds. This makes them effective for facilitating electrochemical reactions and improving the degradation of micropollutants.

Using advanced analytical methods, the scientists were able to explore the complex interactions involved in the degradation of steroid hormones in an EMR. Their findings revealed that pre-adsorption of hormone molecules on the surface of carbon nanotubes did not impede their later degradation. This was attributed to rapid adsorption and effective mass transfer, allowing for efficient removal of micropollutants. The researchers’ analysis provides valuable insights into the mechanisms of electrochemical membrane reactors and offers guidance for enhancing electrochemical strategies for eliminating micropollutants from water.

The study conducted by KIT researchers contributes to the ongoing efforts to address the challenges posed by micropollutants in aquatic environments. By providing a deeper understanding of the degradation mechanisms of steroid hormones in EMRs with carbon nanotube membranes, the researchers offer important insights into improving water treatment processes. Effective removal of micropollutants is essential for safeguarding human health and preserving the ecological balance of aquatic ecosystems. The insights gained from this research can inform future developments in water treatment technology to ensure the supply of clean water for people worldwide.

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