A groundbreaking new chemical process has been developed at the University of California, Berkeley, that has the capability to effectively vaporize plastics that are prevalent in today’s waste stream. This process can convert plastic waste into hydrocarbon building blocks, which can then be utilized to create new plastics. The process works well with the two primary types of post-consumer plastic waste: polyethylene and polypropylene. It also efficiently degrades a mixture of these plastics, offering promise for a circular economy for many disposable plastics.
Polyethylene and polypropylene plastics make up a significant portion of post-consumer plastic waste globally, with a large percentage ending up in landfills or as litter in the environment. In an effort to reduce this waste, researchers have been exploring methods to convert these plastics into more valuable materials, such as monomers used in the production of new plastics. This approach would establish a circular polymer economy for plastics, helping to reduce the reliance on petroleum-based plastics that contribute to greenhouse gas emissions.
The new process developed by the UC Berkeley team replaces expensive, soluble metal catalysts with more cost-effective solid catalysts commonly used in the chemical industry for continuous flow processes. These catalysts are able to efficiently break down various types of polyolefin polymer chains, leaving behind reactive carbon-carbon double bonds that enable the conversion of these polymers into propylene and isobutylene. The process, known as olefin metathesis, is highly efficient, with yields close to 90% for a mixture of polyethylene and polypropylene.
One notable advantage of the new catalysts is that they eliminate the need to remove hydrogen to form a breakable carbon-carbon double bond in the polymer, as required in the researchers’ earlier process for deconstructing polyethylene. This innovative approach allows for the efficient conversion of a mixture of polyethylene and polypropylene into gases, propylene, and isobutylene, with impressive yields. The low cost and high efficiency of the new catalysts make this process a promising solution for recycling hard-to-recycle plastics.
Despite efforts to redesign plastics for easier recycling, the reality is that the world will continue to rely on polyethylene and polypropylene for the foreseeable future. These plastics are affordable and offer desirable properties, making them popular choices for a wide range of products. The ability to establish a circular economy for polyolefins through processes like the one developed at UC Berkeley offers a practical and sustainable solution to address the growing environmental challenges posed by plastic waste.
The successful development of this chemical process represents a significant advancement in the field of plastic recycling. By effectively converting common post-consumer plastics into valuable building blocks for new plastics, this innovative approach has the potential to revolutionize the way plastic waste is managed and reduce the environmental impact of plastic pollution. As researchers continue to explore ways to improve plastic recycling processes, the circular economy model for plastics is gaining momentum as a viable and sustainable solution for managing plastic waste.
